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methyl azide : ウィキペディア英語版
methyl azide

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Methyl azide is a covalent molecule related to hydrazoic acid and other alkyl azides.
It can be prepared by a methylation of sodium azide. The first synthesis was reported in 1905. It decomposes in a first-order reaction:
:CH3N3 → CH3N + N2
Methyl azide might be a potential precursor in the synthesis of prebiotic molecules via nonequilibrium reactions on interstellar ices initiated by energetic galactic cosmic rays (GCR) and photons.
==Safety precautions==
Methyl azide is stable at ambient temperature but may explode when heated. Presence of mercury increases the sensitivity to shock and spark. Incompatible with (dimethyl malonate + sodium methylate); mercury; methanol; sodium azide; dimethyl sulfate; sodium hydroxide; hydrogen azide. When heated to decomposition it emits toxic fumes of NOx.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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